+1 This would be a great way to video chat!
I tried, but OUYA did not recognize it. However, I also tried Skype, and it works, apart from the video part. You can chat, also wit a keyboard (Logitech) connected with the unifying dongle
Email Microsoft, I'm sure they'll help you get 'er goin...
OUYA FORUM List of Working Controllers (Please Contribute!) - http://ouyaforum.com/showthread.php?3673-LIST-Controllers-That-Work-With-OUYA